| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326172 | Journal of Organometallic Chemistry | 2012 | 6 Pages |
Abstract
⺠Theoretical investigation of dimethylgallyl complexes of Co, Rh, Ir. ⺠The M-Ga bonds in the studied complexes are nearly M-Ga single bond. ⺠Bond dissociation energy of the M-Ga bonds increases as Co < Rh < Ir. ⺠Electrostatic interactions are significantly larger than the covalent bonding. ⺠[GaMe2] ligand behaves predominantly as an Ï-donor.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Structure and bonding analysis of dimethylgallyl complexes of cobalt, rhodium and iridium [Me(PMe3)2(Me3GaCl)M(GaMe2)] (MÂ =Â Co, Rh, Ir) and [Me(PMe3)2ClIr(GaMe2)]: A theoretical study](/preview/png/1326172.png "First Page Preview: Structure and bonding analysis of dimethylgallyl complexes of cobalt, rhodium and iridium [Me(PMe3)2(Me3GaCl)M(GaMe2)] (MÂ =Â Co, Rh, Ir) and [Me(PMe3)2ClIr(GaMe2)]: A theoretical study")
Authors
Krishna K. Pandey,