NMR spectra of silatranes and M ← N (M = C, Si, Ge, Sn, Pb) bond lengths in atranes: Substituent effects

The literature data on X substituent influence on the 1H, 29Si and 15N NMR chemical shifts (δ) and coupling constants (J) of Si-substituted silatranes , as well as M–N bond lengths (d) in atranes (M = C, Si, Ge, Sn, Pb) have been analyzed. It was established for the first time that the δ, J and d values depend not only on the inductive and resonance effects but also on the polarizability of X substituents. The polarizability contribution ranges from 8% to 25%.

Graphical abstractThe properties of atranes (NMR chemical shifts and coupling constants, M ← N bond lengths) depend on joint influence of the inductive, resonance, and polarizability effects of X.Figure optionsDownload full-size imageDownload as PowerPoint slide