Article ID Journal Published Year Pages File Type
1326247 Journal of Organometallic Chemistry 2005 7 Pages PDF
Abstract

Kinetically stabilized 3-oxo-1,3-diphosphapropenes were prepared by oxidation of 1,3-diphosphapropenes with m-CPBA or from reaction of the corresponding phosphaethenyllithium with phosphinic chloride. The 3-oxo-1,3-diphosphapropenes were used as P,O-unsymmetrical bidentate ligands and the catalytic activity of the palladium(II) complexes in some cross-coupling reactions was investigated.

Graphical abstractKinetically stabilized 3-oxo-1,3-diphosphapropenes were prepared and used as P,O-unsymmetrical bidentate ligands of dichloropalladium(II) complexes. The chelate complexes were characterized and the catalytic activity for some cross-coupling reactions was investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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