Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326247 | Journal of Organometallic Chemistry | 2005 | 7 Pages |
Abstract
Kinetically stabilized 3-oxo-1,3-diphosphapropenes were prepared by oxidation of 1,3-diphosphapropenes with m-CPBA or from reaction of the corresponding phosphaethenyllithium with phosphinic chloride. The 3-oxo-1,3-diphosphapropenes were used as P,O-unsymmetrical bidentate ligands and the catalytic activity of the palladium(II) complexes in some cross-coupling reactions was investigated.
Graphical abstractKinetically stabilized 3-oxo-1,3-diphosphapropenes were prepared and used as P,O-unsymmetrical bidentate ligands of dichloropalladium(II) complexes. The chelate complexes were characterized and the catalytic activity for some cross-coupling reactions was investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Katsunori Nishide, Hongze Liang, Shigekazu Ito, Masaaki Yoshifuji,