| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326357 | Journal of Organometallic Chemistry | 2005 | 5 Pages |
Abstract
Two [Rh(acac)(CO)(L)] (LÂ =Â carbene) complexes were prepared and evaluated as catalyst precursors in the hydroformylation of 1-hexene. In the presence of an added phosphine or phosphite ligand no added benefit is derived from the presence of the carbene ligand as compared to using [Rh(acac)(CO)2] as catalyst precursor. 31P NMR spectroscopy indicates liberation of the carbene under these conditions.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and characterisation of two novel Rh(I) carbene complexes: Crystal structure of [Rh(acac)(CO)(L1)]](/preview/png/1326357.png "First Page Preview: Synthesis and characterisation of two novel Rh(I) carbene complexes: Crystal structure of [Rh(acac)(CO)(L1)]")
Authors
Michael S. Datt, Jerald J. Nair, Stefanus Otto,