| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326403 | Journal of Organometallic Chemistry | 2012 | 8 Pages |
Abstract
⺠Values of various energy terms decreases via Si > Ge > Sn > Pb. ⺠The electrostatic interaction is almost equal to the orbital interactions. ⺠The Ï-bonding interactions are significantly weaker. ⺠The Ï back-donation is the most dominant interaction in the studied complexes.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Krishna K. Pandey, Pankaj Patidar,
![First Page Preview: Theoretical investigation of Mâ¡E bonds in transition metal-ylidyne complexes trans-[H(PMe3)4Mâ¡ER] (M = Mo, W; E = Si, Ge, Sn, Pb; R = Mes, Xylyl) Theoretical investigation of Mâ¡E bonds in transition metal-ylidyne complexes trans-[H(PMe3)4Mâ¡ER] (M = Mo, W; E = Si, Ge, Sn, Pb; R = Mes, Xylyl)](/preview/png/1326403.png)