Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326433 | Journal of Organometallic Chemistry | 2005 | 4 Pages |
Abstract
The palladium-catalyzed borylation reaction of 1-alkenyl halides with diisopropylaminoborane leads efficiently and stereospecifically to the corresponding trans-1-alkenyl(diisopropylamino)boranes in good yields.
Graphical abstractBsp2–HBsp2–H containing (E)-1-alkenyl boron derivatives as stable and isolable species are accessible stereospecifically in medium to high yields from 1-alkenyl halides via a palladium-catalyzed borylation reaction involving diisopropylaminoborane as an efficient BH transferring agent.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Lisenn Euzénat, David Horhant, Cédric Brielles, Gilles Alcaraz, Michel Vaultier,