Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326434 | Journal of Organometallic Chemistry | 2005 | 7 Pages |
Anion binding by the pyroborates (catB)2O (1, cat = O2C6H4-1,2) and (S,S-Ph2C2H2O2B)2O (2) has been investigated by spectroscopic, structural and titration methods. 1 has been shown to act as a bifunctional Lewis acid, exemplified by the complementary (1:1) binding of bidentate bases such as acetate and dihydrogen phosphate. The former complex has been characterized in the solid state by X-ray diffraction and a binding constant of 1500 ± 550 M−1 determined in chloroform solution. The reaction of 2 with acetate, by contrast, leads to breakdown of the Lewis acid chelate and to the formation of the homochiral borate anion [(S,S-Ph2C2H2O2)2B]− in good yield (84% based on the chiral component).
Graphical abstractAnion binding by the pyroborates (catB)2O (1, cat = O2C6H4-1,2) and (S,S-Ph2C2H2O2B)2O (2) has been investigated by spectroscopic, structural and titration methods; 1 has been shown to act as a bifunctional Lewis acid in the complementary (1:1) binding of acetate both in the solid state and in solution (for which a binding constant of 1500 ± 550 M−1 has been determined).Figure optionsDownload full-size imageDownload as PowerPoint slide