| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326507 | Journal of Organometallic Chemistry | 2012 | 6 Pages |
Abstract
⺠2,5-Disubstituted 1-zirconacyclopent-3-yne compounds isomerized from trans to cis, and vice versa. ⺠A dinuclear complex of 1,4-bis(trimethylsilyl)butatriene was synthesized, although it was unimportant for the isomerization. ⺠The isomerization reaction was first order in zirconium species. ⺠Kinetic isotope effect (kH/kD = 1.8) was observed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Noriyuki Suzuki, Kosuke Nishimura, Nozomu Ohara, Masayoshi Nishiura, Yoshiro Masuyama,