| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326523 | Journal of Organometallic Chemistry | 2007 | 6 Pages |
Abstract
Several types of (thio)phosphonylimines were synthesized and their reaction with diethylzinc was investigated in detail. An interesting and distinct chemoselectivity between hydrogen-addition and ethyl-addition to imine double bond is disclosed. The corresponding reduction product was obtained in excellent yield in nonpolar solvent toluene. However, the corresponding ethylation product was obtained exclusively in the presence of strongly coordinative additive N,N,Nâ²,Nâ²-tetramethylethylenediamine (TMEDA).
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Xinpeng Ma, Xinyuan Xu, Chungui Wang, Guofeng Zhao, Zhenghong Zhou, Chuchi Tang,