| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326612 | Journal of Organometallic Chemistry | 2011 | 4 Pages |
Abstract
⺠[RhCl(cod)]2 with 1,3,5-triaza-7-phosphaadamantane acts as active branch-selective catalyst for C-allylation of acetylacetone by allylic carbonates in water/ethyl acetate biphasic system. Either crotyl or 1-methylallyl carbonates gives branch allylation product. An SN2 reaction of acetylacetone to a common 3-methylallylrohodium intermediate is considered to be responsible for this selectivity.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nobuyuki Komine, Kohtaro Ishiguro, Sachiyo Kanai, Masafumi Hirano, Sanshiro Komiya,