| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326662 | Journal of Organometallic Chemistry | 2011 | 4 Pages |
Abstract
The oxidative electrochemistry of P(CH2Fc)3 and three of its derivatives was examined. The electrochemistry of these compounds is sensitive to the functionality added to the phosphorus lone pair and the supporting electrolyte used.
Graphical abstractThe oxidative electrochemistry of P(CH2Fc)3 and three of its derivatives was examined. The functionality added to the phosphorus as well as the supporting electrolyte used influence the electrochemistry of these compounds.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Oxidation of [P(CH2Fc)4]+ displays four waves in CH2Cl2 with [NBu4][TFAB]. ► Oxidation of P(CH2Fc)3 and [HP(CH2Fc)3]+ is not straight forward. ► Oxidation of O = P(CH2Fc)3 displays one wave.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ashley R. Seibert, Matthew F. Cain, David S. Glueck, Chip Nataro,