| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326743 | Journal of Organometallic Chemistry | 2007 | 9 Pages |
Abstract
A comparison of epoxide, aldehyde and peroxide initiators for Cp2TiCl-catalyzed living radical styrene polymerizations was performed by investigating the effect of reagent stoichiometry and temperature on the initiator efficiency and polydispersity. An optimum was observed for [Styrene]/[Initiator]/[Cp2TiCl2]/[Zn] = [50-200]/[1]/[2-3]/[4-6] at 70-90 °C.
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Alexandru D. Asandei, Yanhui Chen, Isaac W. Moran, Gobinda Saha,