Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1326744 | Journal of Organometallic Chemistry | 2007 | 8 Pages |
Abstract
Oxidation of Cr[(Me3SiN)2CPh]2 (1) with silver benzoate or iodine provides neutral Cr(III) bis(benzamidinato) complexes, which react with C3H5MgCl to form the η3-allyl complex. The reaction of 1 with excess allyl benzoate was monitored by UV-vis spectroscopy. The X-ray structures of 2, 3, and 5 are reported.
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Authors
Beth A. Dykerman, Joshua J. Smith, Erin M. McCarvill, Amanda J. Gallant, Natasha D. Doiron, Brian D. Wagner, Hillary A. Jenkins, Brian O. Patrick, Kevin M. Smith,