| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326754 | Journal of Organometallic Chemistry | 2007 | 10 Pages |
Abstract
The sulfur-centered chemistry of CpâRu(III)L (LÂ =Â [S(CH2CH2Sâ)2] and [{HN(CH2CH2Sâ)2]) is dominated by redox interactions, initiated by alkylation and iodine oxidation. The Ru thiyl radicals so generated led to S-S coupling reactions, and the facile reversible homolytic dissociation of the S-S bond, substantiated by electrochemical data, contributed significantly to the rich chemistry of these systems.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Richard Yee Cheong Shin, Hui Shan Sim, Lai Yoong Goh, Richard D. Webster,