| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326779 | Journal of Organometallic Chemistry | 2009 | 4 Pages |
Abstract
Efficient silylative coupling of linear vinyl-substituted oligo- and polysiloxanes with styrene in the presence of [RuHCl(CO)(PPh3)3] (1) and particularly [RuHCl(CO)(PCy3)2] (2) combined with copper(I) chloride is described. Treatment of styrene, with terminal or side vinyl group at siloxane skeleton catalyzed by [RuHCl(CO)(PCy3)2]/CuCl results in the quantitative and selective formation of respective silylative coupling products.
Graphical abstractEfficient silylative coupling of linear vinyl-substituted oligo- and polysiloxanes with styrene in the presence of ruthenium hydride complexes is described.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Patrycja Żak, Monika Skrobańska, Cezary Pietraszuk, Bogdan Marciniec,