| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326786 | Journal of Organometallic Chemistry | 2009 | 5 Pages |
Abstract
The first carbosilane dendrimer functionalized with P-stereogenic diphosphine ligands was prepared along with its cationic rhodium derivative. A mononuclear rhodium model compound was also synthesized. Both species were used as catalysts in the hydrogenation of dimethylitaconate and the results compared with those obtained with the related rhodium-containing P-stereogenic monophosphine dendrimers.
Graphical abstractThe first dendrimer functionalized with P-stereogenic diphosphine ligands has been prepared and decorated with Rh(COD) fragments for catalytic studies.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
L.I. Rodríguez, O. Rossell, M. Seco, G. Muller,