| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326841 | Journal of Organometallic Chemistry | 2007 | 4 Pages |
Abstract
Tri-tert-butoxyaluminium (tetra-tert-butoxytitanium) and tert-butylhydroperoxide (1:2) under mild conditions (20 °C) in C6H6, C6H5Cl or CCl4 generate oxygen in a yield â¼80%. â¼50% of the oxygen is in the electron-excited singlet state. System triphenylbismuth-tert-butylhydroperoxide (1:3) forms an η2-peroxocomplex. XOOOBu-t [X = (t-BuO)2Al, (t-BuO)3Ti] and Ph3Bi(η2O2) demonstrate high oxidizing activity.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Elena A. Zaburdaeva, Viktor A. Dodonov, Larisa P. Stepovik,