| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326864 | Journal of Organometallic Chemistry | 2008 | 6 Pages |
Abstract
Treatment of 9-(2-methoxyethyl)fluorene, C13H9CH2CH2OMe, with potassium hydride in THF/toluene in the presence of 18-crown-6 afforded orange-red crystalline K(18-crown-6)C13H8CH2CH2OMe. A “constrained geometry”-type praseodymium complex containing the 9-(2-methoxyethyl)fluorenyl ligand, (COT)Pr(C13H8CH2CH2OMe)(THF), was prepared by treatment of dimeric [(COT)Pr(μ-Cl)(THF)2]2 (COT = η8-cyclooctatetraenyl) with in situ prepared KC13H8CH2CH2OMe and structurally characterized by single-crystal X-ray diffraction.
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Authors
Ahmad Zaeni, Falk Olbrich, Axel Fischer, Frank T. Edelmann,