| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326892 | Journal of Organometallic Chemistry | 2010 | 7 Pages |
Abstract
[(COD)Ru(2-methylallyl)2] acts as a substrate for the synthesis of the first structurally characterized mononuclear ruthenium complexes of the general formula [(COD)Ru([RNC(H)-C(H)C(Ph)]2 in which the imine coordinate as enyl-imino ligands. In addition, [(COD)Ru(2-methylallyl)2] turns out to be a highly effective precatalyst in catalytic C-H activation/C-C coupling reactions of the same imines.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![{(COD)Ru[RNC(H)-C(H)C(Ph)]2} (RMe, Et): The first structurally characterized mononuclear ruthenium complexes with enyl-imino ligands and their relevance in ruthenium catalyzed C-H activation reactions](/preview/png/1326892.png "First Page Preview: {(COD)Ru[RNC(H)-C(H)C(Ph)]2} (RMe, Et): The first structurally characterized mononuclear ruthenium complexes with enyl-imino ligands and their relevance in ruthenium catalyzed C-H activation reactions")
Authors
Linda Schweda, Andreas Nader, Roberto Menzel, Tobias Biletzki, Christopher Johne, Helmar Görls, Wolfgang Imhof,