| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326957 | Journal of Organometallic Chemistry | 2006 | 6 Pages |
Abstract
The complexes CpRu(L)(Lâ²)SH react with O-alkyl oxalyl chlorides to form the corresponding O-alkylthiooxalate complexes CpRu(L)(Lâ²)SCOCO2R (L = Lâ²Â = PPh3 (1), 12dppe (2); L = PPh3, Lâ²Â = CO (3); R = Me (a), Et (b)). The reactions of the hydrosulfido complexes with half equivalent of oxalyl chloride produce [CpRu(L)(Lâ²)SCO]2 (L = Lâ²Â = PPh3 (4), 12dppe (5); L = PPh3, Lâ²Â = CO (6)). The crystal structures of CpRu(PPh3)2SCOCO2Me (1a) and CpRu(dppe)SCOCO2Et (2b) are reported.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mohammad El-khateeb, Khaled Shawakfeh, Tobias Rüffer, Heinrich Lang,