Article ID Journal Published Year Pages File Type
1327059 Journal of Organometallic Chemistry 2006 4 Pages PDF
Abstract
The monosubstituted clusters RuOs3(μ-H)2(CO)12(EPh3) (where E = P, As, Sb) exhibit isomers in which the group 15 ligand is on an Os or an Ru vertex. Evidence is presented for hydride fluxionality and EPh3 ligand migration. These processes have been examined by variable temperature NMR studies, and the kinetic parameters estimated.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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