Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327059 | Journal of Organometallic Chemistry | 2006 | 4 Pages |
Abstract
The monosubstituted clusters RuOs3(μ-H)2(CO)12(EPh3) (where E = P, As, Sb) exhibit isomers in which the group 15 ligand is on an Os or an Ru vertex. Evidence is presented for hydride fluxionality and EPh3 ligand migration. These processes have been examined by variable temperature NMR studies, and the kinetic parameters estimated.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Leonard Joachim Pereira, Weng Kee Leong,