| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327072 | Journal of Organometallic Chemistry | 2006 | 4 Pages |
Abstract
Subtle differences in the electron-richness of nitrogen atoms in 1,1′-bis(phosphoranylidenamino)ferrocenes can change the coordination geometry of their palladium(II) complexes from cis to trans. Trans complexation results in concomitant formation of a relatively short dative Fe–Pd bond of 2.67 Å.
Graphical abstractSubtle differences in the electron-richness of nitrogen atoms in 1,1′-bis(phosphoranylidenamino)ferrocenes can change the coordination geometry of their palladium(II) complexes from cis to trans. Trans complexation results in concomitant formation of a relatively short dative Fe–Pd bond of 2.67 Å.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Costa Metallinos, Deanna Tremblay, Fred B. Barrett, Nicholas J. Taylor,