| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327084 | Journal of Organometallic Chemistry | 2008 | 6 Pages |
Abstract
Four new BINOL-based thiazole (thiadiazole) thioether ligands (S)-1, (S)-2, (S,S)-3 and (S)-4 were prepared. When their catalytic effectiveness was tested, good results (up to 93% ee and 97% yield) were obtained in the asymmetric addition of diethylzinc to aldehydes while poor results were obtained in the asymmetric conjugate addition of diethylzinc to enones.
Graphical abstractFour new BINOL-based thiazole (thiadiazole) thioether ligands were prepared and their asymmetric catalytic effectiveness was tested.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Zhi-Bing Dong, Bing Liu, Cao Fang, Jin-Shan Li,