Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327111 | Journal of Organometallic Chemistry | 2010 | 4 Pages |
Abstract
Reduction of benzal halide derivatives and α,α,α,-trichlorotoluene by magnesium powder in DMAc affords α-halocarbanions which then react with triethylborane to give alkylated products. After oxidation with H2O2-NaOH, secondary or tertiary alcohols are obtained. Under the same conditions, 1,1-diphenylpropane is obtained from α,α-dichlorodiphenylmethane.
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sylvie Condon, Jean-Yves Nédélec,