Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327130 | Journal of Organometallic Chemistry | 2006 | 4 Pages |
Abstract
A one-pot hydrostannation/Stille coupling sequence amenable to the employment of acid chloride electrophiles has been developed. In this protocol, palladium mediated alkyne hydrostannations using Me3SnF/PMHS as an in situ trimethyltin hydride source are followed by the addition of the acid chloride to afford a variety of α,β-unsaturated ketones in a single pot.
Graphical abstractA one-pot hydrostannation/Stille coupling sequence amenable to the employment of acid chloride electrophiles has been developed.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kyoungsoo Lee, William P. Gallagher, Elli A. Toskey, Wenzheng Chong, Robert E. Maleczka Jr.,