Article ID Journal Published Year Pages File Type
1327136 Journal of Organometallic Chemistry 2006 5 Pages PDF
Abstract

Reaction of SnCl4 with Sn(CH2CHCH2)4 in the presence of water and monothiobinaphthol [2,2′-C20H12(OH)(SH)] allows the formation of a selective catalyst for the allylation of ketones (up to 94% e.e.).

Graphical abstractUse of Sn(allyl)4/SnCl4 mixtures allows rapid access to a selective asymmetric allylation catalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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