Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327136 | Journal of Organometallic Chemistry | 2006 | 5 Pages |
Abstract
Reaction of SnCl4 with Sn(CH2CHCH2)4 in the presence of water and monothiobinaphthol [2,2′-C20H12(OH)(SH)] allows the formation of a selective catalyst for the allylation of ketones (up to 94% e.e.).
Graphical abstractUse of Sn(allyl)4/SnCl4 mixtures allows rapid access to a selective asymmetric allylation catalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Oscar Prieto, Simon Woodward,