Article ID Journal Published Year Pages File Type
1327153 Journal of Organometallic Chemistry 2006 6 Pages PDF
Abstract
Five new chiral germanium substituted diethyltin dicarboxylates have been synthesized and characterized by multinuclear (1H, 13C, 119Sn) NMR, 119mSn Mössbauer and IR spectroscopy.2R31GeCH(R2)CH2COOH+Et2SnO→refluxToluene[R31GeCH(R2)CH2COO]2SnEt2+H2OThe X-ray structure of the precursor I4 clearly depicts chiral center in the carboxylate portion of the compound which was further confirmed by the measurement of rotation angle.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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