| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327179 | Journal of Organometallic Chemistry | 2007 | 7 Pages |
Abstract
The PdI–PdI bonded complex [Pd2(CH3CN)6][SbF6]2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined.
Graphical abstractThe binary dinuclear Pd(I) CH3CN complex is catalytically active towards Suzuki cross-coupling reactions under mild conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Xiaoyan Han, Zhiqiang Weng, T. S. Andy Hor,