Article ID Journal Published Year Pages File Type
1327261 Journal of Organometallic Chemistry 2007 6 Pages PDF
Abstract

The photochemistry of octaisopropylcyclotetragermane was studied by laser flash photolysis and trapping experiments. Upon irradiation of the cyclotetragermane, the main reaction was a ring opening to form octaisopropyltetragermane-1,4-diyl biradical (λmax = 310 and 550 nm), but generations of diisopropylgermylene and tetraisopropyldigermene are negligible.

Graphical abstractThe photochemistry of octaisopropylcyclotetragermane was studied by laser flash photolysis and trapping experiments. Upon irradiation of the cyclotetragermane, the main reaction was a ring opening to form octaisopropyltetragermane-1,4-diyl biradical (λmax = 310 and 550 nm), but generations of diisopropylgermylene and tetraisopropyldigermene are negligible.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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