| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327346 | Journal of Organometallic Chemistry | 2007 | 8 Pages |
Various mono Cp∗ type titanium mononuclear complexes (1–5) and dinuclear complexes (6 and 7) containing non-Cp type chelate ligand, picolinate group, which has multi-binding sites of N and O atoms were synthesized and fully characterized by 1H and 13C NMR spectroscopy, mass spectroscopy, elemental analysis, and X-ray diffraction study. The 1 and 2/MMAO catalytic systems for ethylene polymerization exhibited a moderate activity and gave the polyethylenes with broad molecular weight distributions.
Graphical abstractVarious mono Cp type titanium mononuclear complexes (1–5) and dinuclear complexes (6 and 7) containing 2-pyridinecarboxylate ligand were synthesized and structurally characterized. The 1 and 2/MMAO catalytic systems for ethylene polymerization exhibited a moderate activity and produced polyethylenes with multi-modal molecular weight distributions.Figure optionsDownload full-size imageDownload as PowerPoint slide
