| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327394 | Journal of Organometallic Chemistry | 2009 | 4 Pages |
Abstract
A new method of 1-fluorosilatrane synthesis on the basis of silicon tetrafluoride complexes obtained from SiO2 is offered. Chemical properties of 1-fluorosilatrane in reactions of nucleophilic substitution are investigated. It is shown that fluorine can be substituted by O-nucleophiles (lithium methoxide, isopropoxide and phenoxide) and C-nucleophile (lithium phenylacetylenide).
Graphical abstractSilicon tetrafluoride complexes prepared from SiO2 react with triethanolamine in a presence of silica to form 1-fluorosilatrane 4. Fluorine atom in 4 can be substituted by O- and C-nucleophiles.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sergey A. Lermontov, Alena N. Malkova, El’mira Kh. Lermontova, Andrei V. Churakov,