Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327398 | Journal of Organometallic Chemistry | 2009 | 6 Pages |
Abstract
In order to study the performance of organometallic complexes in the telomerization of butadiene with methanol in aqueous medium, we synthesized and characterised hydrosoluble palladium complexes. [(π-allyl)Pd(TPPTS)2]+Cl− complex exhibited strong stability as no degradation was observed after storage at room temperature under air atmosphere for weeks. TON’s up to 36 000 were achieved at 50 °C.
Graphical abstractCationic hydrosoluble palladium complexes were prepared. They were stable at room temperature under air atmosphere for weeks. They were efficient in the telomerization of butadiene with methanol in the presence of water under mild conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Julien Mesnager, Emile Kuntz, Catherine Pinel,