| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327406 | Journal of Organometallic Chemistry | 2009 | 5 Pages |
Abstract
Pyridine-N ligation was able to tune the redox properties of the diiron centers of model complexes: Ï-backdonation renders the uneven electron density of the diiron core to pyridine ring, and under excessive HOAc, model complex was proven to be reductive active at rather low first reduction potential.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Terminal pyridine-N ligation at [FeFe] hydrogenase active-site mimic](/preview/png/1327406.png "First Page Preview: Terminal pyridine-N ligation at [FeFe] hydrogenase active-site mimic")
Authors
Yue Zhang, Ming-Qiang Hu, Hui-Min Wen, You-Tao Si, Cheng-Bing Ma, Chang-Neng Chen, Qiu-Tian Liu,