Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327409 | Journal of Organometallic Chemistry | 2009 | 7 Pages |
Abstract
The paper reports the ability of the mercury anticrown (o-C6F4Hg)3 (1) to form complexes with ethanol and THF. In the case of ethanol, a pyramidal 1:1 complex, {[(o-C6F4Hg)3](EtOH)}, has been isolated. In the case of THF, the complexes {[(o-C6F4Hg)3](THF)n} (n = 1-4), containing pyramidal (n = 1) or bipyramidal (n = 2-4) fragments in their structures, are produced. An unusual sandwich complex of 1 with bis-2,2â²-tetrahydrofuryl peroxide is also described.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
I.A. Tikhonova, K.I. Tugashov, F.M. Dolgushin, A.A. Korlyukov, P.V. Petrovskii, Z.S. Klemenkova, V.B. Shur,