Article ID Journal Published Year Pages File Type
1327466 Journal of Organometallic Chemistry 2005 7 Pages PDF
Abstract

Ionic liquids are salts that are liquid at or near room temperature. Their wide liquid range, good thermal stability, and very low vapor pressure make them attractive for numerous applications. The general approach to creating ionic liquids is to employ a large, unreactive, low symmetry cation with and an anion that largely controls the physical and chemical properties. The most common cations used in ionic liquids are N-alkylpyridinium and N,N′-dialkylimidazolium. Another very effective cation for the creation of ionic liquids is tetraalkylphosphonium, [PR1R2R3R4]+. The alkyl groups, Rn, generally are large and not all the same. The halide salts of several phosphonium cations are available as starting materials for metathesis reactions used to prepare ionic liquids. The large phosphonium cations can combine with relatively large anions to make viscous but free flowing liquids with formula mass greater than 1000 g mol−1. Some other more massive salts are waxes and glasses. The synthesis and the physical, chemical, and optical properties of phosphonium-ionic liquids having anions with a wide range of masses were measured and are reported here.

Graphical abstractA new class of phosphonium-based room temperature ionic liquids (RTIL) has been synthesized and characterized. The salts contain conjugated organic anions, anionic dyes, and metal–ligand complexes. The viscosities and low temperature glass transitions can be controlled by cation size and symmetry, while the optical properties can be varied through selection of a number of anions.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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