| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327469 | Journal of Organometallic Chemistry | 2005 | 6 Pages |
Abstract
The intermediacy of metathiophosphonate PhPSO in the reaction of N-tert-butyl-P-phenylphosphonamidothioic acid with alcohols (MeOH, BuOH, PriOH, ButOH) is proposed on the basis of nitrogen and hydrogen kinetic isotope effects, as well as semiempirical PM3 calculations. For the reaction with methanol the alternative addition-elimination mechanism cannot be excluded.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Stefan Jankowski, Adam Mazur, Tomasz Nonas, Barbara Vokal,