Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327569 | Journal of Organometallic Chemistry | 2009 | 6 Pages |
Oxidation of N,N,N′,N′-tetrakis(diphenylphosphino)ethylendiamine (1) with elemental sulfur and selenium gives the corresponding sulfide and selenide, respectively, [(Ph2P(E))2NCH2CH2N(P(E)Ph2)2] (E: S 1a, Se 1b). Complexes of 1 [(M2Cl4){(Ph2P)2NCH2CH2N(PPh2)2}] (M: Ni(II) 1c, Pd(II) 1d, Pt(II) 1e) were prepared by the reaction of 1 with NiCl2 or [MCl2(COD)] (M = Pd, Pt). The new compounds were characterized by NMR, IR spectroscopy and elemental analysis. The catalytic activity of Pd(II) complex 1d was tested in the Suzuki coupling reaction and Heck reaction. The palladium complex 1d catalyses the Heck reaction between styrene and aryl bromides as well as Suzuki coupling reaction between phenylboronic acid and arylbromides affording stilbenes and biphenyls in high yield, respectively.
Graphical abstractMetal complexes {Ni (II), Pd (II) and Pt (II)} and oxidation products (sulfide and selenide) of N,N,N′,N′-tetrakis(diphenylphosphino)ethylendiamine, [(Ph2P)2NCH2CH2N(PPh2)2] (1) have been prepared and characterized. The catalytic behaviour of the Pd(II) complex was investigated in the Suzuki coupling and Heck reactions.Figure optionsDownload full-size imageDownload as PowerPoint slide