Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327646 | Journal of Organometallic Chemistry | 2006 | 9 Pages |
Abstract
Mixed μ-phosphido or μ-thiolato μ-halo-dimolybdenum(III) compounds [Mo2Cp2(μ-SMe)2(μ-X)(μ-Y)] (X = PPh2, Y = Cl (1); X = SCH3, Y = Br (3), I (4)) have been studied. The influence of the bridging groups on the structures and electrochemical behaviour of the complexes [Mo2Cp2(μ-SMe)2(μ-X)(μ-Y)] 1-4 has been investigated. The X-ray structure of the original Mo5 system [{Mo2Cp2Br(μ-O)(μ-SMe)2}2(μ-MoO4)] (5), is reported.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Christine Le Roy, François Y. Pétillon, Kenneth W. Muir, Philippe Schollhammer, Jean Talarmin,