Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327718 | Journal of Organometallic Chemistry | 2006 | 4 Pages |
Abstract
W2COT(NMe2)4 and 1,2-W2Cp2(NMe2)4 undergo thiolysis with excess ButSH to produce the known thiolate compound anti-1,2-W2(SBut)2(NMe2)4. The solid state structure of the thiolate product was determined and it was shown to be isostructural with the Mo analogue. The preferential W-C activation observed during thiolysis is contrasted with the alcoholysis reactions of the same precursors.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Malcolm H. Chisholm, Judith C. Gallucci, Carl B. Hollandsworth,