Article ID Journal Published Year Pages File Type
1327725 Journal of Organometallic Chemistry 2006 9 Pages PDF
Abstract

1,3- and 1,4-Bis[tris(trimethylsilyl)silylethynyl]benzenes as well as 1,3,5-tris[tris(trimethylsilyl)silylethynyl]benzene were synthesized employing Sonogashira cross-coupling conditions. All three molecules underwent facile di- or trimetalation with potassium tert-butoxide to afford the respective oligosilyldi- and trianions.

Graphical abstractThe synthesis of multiply anionic oligosilanes was investigated. 1,3- and 1,4-bis[tris(trimethylsilyl)silylethynyl]benzenes as well as 1,3,5-tris[tris(trimethylsilyl)silylethynyl]benzene could be obtained employing Sonogashira cross-coupling conditions. All three molecules underwent facile di- or trimetalation with potassium tert-butoxide to afford the respective oligosilyldi- and trianions.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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