Syntheses, crystal structures and DFT studies of [Me3EM(CO)5] (E = Sb, Bi; M = Cr, W), cis-[(Me3Sb)2Mo(CO)4], and [tBu3BiFe(CO)4]

Syntheses of [Me3SbM(CO)5] [M = Cr (1), W (2)], [Me3BiM(CO)5] [M = Cr (3), W (4)], cis-[(Me3Sb)2Mo(CO)4] (5), [tBu3BiFe(CO)4] (6), crystal structures of 1–6 and DFT studies of 1–4 are reported.

Graphical abstractThe syntheses and the molecular structures of [Me3EM(CO)5] [E = Sb, Bi; M = Cr, W], cis-[(Me3Sb)2Mo(CO)4], and [tBu3BiFe(CO)4] are reported. The complexes [Me3EM(CO)5] [E = Sb, Bi; M = Cr, W] were investigated by DFT methods.Figure optionsDownload full-size imageDownload as PowerPoint slide