| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327801 | Journal of Organometallic Chemistry | 2009 | 5 Pages |
Abstract
A new reaction of P-alkoxypalladation was found. 2,5-Diphenylphosphacymantrene reacts with Na2PdCl4 and NaOAc in MeOH or EtOH to give P-methoxy or P-ethoxy derivatives with Pd2Cl2 dimeric core. The products 2 and 3 were characterized by 1H, 31P, 13C NMR spectra and X-ray crystal structure data.
Graphical abstractA new reaction of P-alkoxypalladation was found. 2,5-Diphenylphosphacymantrene reacts with Na2PdCl4 and NaOAc in MeOH or EtOH to give P-methoxy or P-ethoxy derivatives with Pd2Cl2 dimeric core. The products 2 and 3 were characterized by 1H, 31P, 13C NMR spectra and X-ray crystal structure data.Figure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Аllan G. Ginzburg, Vasily V. Bashilov, Fedor M. Dolgushin, Alexander F. Smol’yakov, Аlexander S. Peregudov, Viatchtslav I. Sokolov,