Article ID Journal Published Year Pages File Type
1327830 Journal of Organometallic Chemistry 2005 6 Pages PDF
Abstract
Reaction of the chiral amine (S)-N-(α-methylbenzyl)allylamine with n-BuLi and n-BuK in the presence of thf produces crystals of the N and C metallated heterobimetallic tetramer, {[(S)-α-(PhC(H)Me)(CH2CH)CHK)N]Li · (thf)}4. The three different K+ cations in the asymmetric unit show differing coordination environments dependent on preferential binding with either thf molecules or available π electron density.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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