Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1327830 | Journal of Organometallic Chemistry | 2005 | 6 Pages |
Abstract
Reaction of the chiral amine (S)-N-(α-methylbenzyl)allylamine with n-BuLi and n-BuK in the presence of thf produces crystals of the N and C metallated heterobimetallic tetramer, {[(S)-α-(PhC(H)Me)(CH2CH)CHK)N]Li · (thf)}4. The three different K+ cations in the asymmetric unit show differing coordination environments dependent on preferential binding with either thf molecules or available Ï electron density.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Philip C. Andrews, Simone M. Calleja, Melissa Maguire,