| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327841 | Journal of Organometallic Chemistry | 2008 | 6 Pages |
Abstract
Density functional theory reveals multiple pathways for intramolecular hydride migration between metal and ligand in cyclopentadienyl and indenyl iron carbonyl complexes. Facile ring slippage in the indenyl case opens up a low-energy channel for transfer of hydride from CO to iron, and hence for decomposition of transient formyl species.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hakim Ahmed, John E. McGrady,