Article ID Journal Published Year Pages File Type
1327862 Journal of Organometallic Chemistry 2005 10 Pages PDF
Abstract

A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations.

Graphical abstractCarbon-centered tris(pentafluorophenyl)silyl derivatives have been prepared and studied by X-ray diffraction analysis.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
, , , , , ,