| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327930 | Journal of Organometallic Chemistry | 2005 | 6 Pages |
The preparation of palladium (II) complexes having sterically congested azetidines as ligands is described. Diastereomerically pure α-alkylamino and α-alkylimino azetidines react with Na2PdCl4 to afford the corresponding bidendate Pd(II) complexes, whereas 2-cyano azetidines can be used to access bidendate Pd(II) complexes containing an amino-imidate moiety. Preliminary study of the catalytic activity of these new complexes in the Suzuki cross-coupling reaction is presented.
Graphical abstractPalladium (II) complexes bearing sterically congested azetidines as ligands have been prepared and characterized. Catalytic systems based on diamine, amino-imine and amino-imidate ligands have been tested in the Suzuki cross-coupling reaction.Figure optionsDownload full-size imageDownload as PowerPoint slide
