| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327938 | Journal of Organometallic Chemistry | 2005 | 4 Pages |
Abstract
The versatility of the palladium (II) chloride/organosilane system has been tested in the transformation of alcohols to the corresponding silyl ethers and the subsequent deprotection of triethylsilyl ethers to the parent alcohols. The reaction takes place under mild conditions and affords high yields.
Graphical abstractSilylethers are prepared in high yields by reaction of alcohols and different silanes in the presence of palladium (II) chloride catalyst at room temperature. Moreover, PdCl2/Et3SiH system was found very efficient for the deprotection of triethylsilyl ethers in ethanol.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Maryam Mirza-Aghayan, Rabah Boukherroub, Mohammad Bolourtchian,