Article ID Journal Published Year Pages File Type
1327973 Journal of Organometallic Chemistry 2008 5 Pages PDF
Abstract
The reaction between RuCl(PPh3)2Cp∗ and {Cu(CCPh)}n in refluxing benzene afforded Ru2Cu2(C2Ph)5H2(Cl)(PPh3)Cp∗2, which contains an unusual tetramer of the phenylethynyl group which interacts with an Ru-Cu-Cu…Ru chain. The second Ru atom is part of a ruthenocenyl moiety which interacts weakly with the second Cu atom, and bears a vinylidene which bridges an Ru-Cu vector.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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