Article ID Journal Published Year Pages File Type
1327980 Journal of Organometallic Chemistry 2008 7 Pages PDF
Abstract
LAlEt(OH) (2; L = HC[C(Me)N(Ar)]2; Ar =  2,6-iPr2C6H3) was synthesized by controlled hydrolysis of LAlEtCl (1). Treatment of 2 with Cp2ZrMe2 and Cp3M afforded heterobimetallic oxides LAlEt(μ-O)ZrMeCp2 (3) and LAlEt(μ-O)M(THF)Cp2 (M = Yb, 4; Er, 5; Dy, 6; Y, 7). Compound 3 exhibits good catalytic activity in ethylene polymerization.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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