| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1327983 | Journal of Organometallic Chemistry | 2008 | 16 Pages |
Abstract
Hemilability and nonrigidity in a series of mixed P,PS donor ligands has been studied in the complexes [Pd(P,PS)Cl2], [Pd(η3-C3H5)(P,PS)][SbF6], and [Rh(cod)(P,PS)][SbF6] (P,PS = Ph2P-Q-P(S)Ph2). The effect of bite angle, the rigidity of the ligand backbone, and the role of the ancillary ligands are discussed.
Graphical abstractHemilability and nonrigidity in a series of mixed P,PS donor ligands has been studied in the complexes [Pd(P,P=S)Cl2], [Pd(η3-C3H5)(P,P=S)][SbF6], and [Rh(cod)(P,PS)][SbF6] (P,PS = Ph2P-Q-P(S)Ph2). The effect of bite angle, the rigidity of the ligand backbone, and the role of the ancillary ligands are discussed.Figure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
J.W. Faller, Suzanna C. Milheiro, Jonathan Parr,